Issue 45, 2024

Appropriation of group II metals: synthesis and characterisation of the first alkaline earth metal supported transition metal carbonite complexes

Abstract

Nickel carbonite complexes supported by alkaline earth metals have been accessed via salt-metathesis of the corresponding alkali metal precursors. The new complexes undergo Schlenk-like exchange reactions in solution which have been investigated by NMR spectroscopy. Also their reactivity towards epoxides and carbon monoxide was studied.

Graphical abstract: Appropriation of group II metals: synthesis and characterisation of the first alkaline earth metal supported transition metal carbonite complexes

Supplementary files

Article information

Article type
Communication
Submitted
10 apr 2024
Accepted
07 mai 2024
First published
07 mai 2024
This article is Open Access
Creative Commons BY license

Chem. Commun., 2024,60, 5816-5819

Appropriation of group II metals: synthesis and characterisation of the first alkaline earth metal supported transition metal carbonite complexes

S. Wolff, A. Ponsonby, A. Dallmann, C. Herwig, F. Beckmann, B. Cula and C. Limberg, Chem. Commun., 2024, 60, 5816 DOI: 10.1039/D4CC01682C

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