Issue 6, 2023

Semi-quantitative determination of active sites in heterogeneous catalysts for photo/electrocatalysis

Abstract

Catalysis is a widely applied process due to its predominant role in the chemical industry. Developing highly active exposed facets via defect engineering is considered to be the most promising strategy for optimizing the electrical and optical properties of catalysts to improve their catalytic activity. Therefore, quantitative determination and calculation of the concentration of defect structures related to the highly exposed active crystal plane provided an efficient route for elucidating the catalytic active sites, and has attracted increasing attention. This work not only summarizes the existing defect characterization methods and the calculation methods of defect concentrations reported in recent years but also proposes a semi-quantitative method based on X-ray absorption fine structure (XAFS) and related methods for the determination and classification of active sites related to the active surface, which can be applied for the semi-quantitative calculation of defect concentrations in widely used metals and metal oxides. In addition, we emphasize the deficiencies of current defect concentration quantitative methods and look forward to the future development of defect characterization methods under working conditions. This review further reveals the structure–activity relationship between the content of active sites and the reaction performance.

Graphical abstract: Semi-quantitative determination of active sites in heterogeneous catalysts for photo/electrocatalysis

Article information

Article type
Review Article
Submitted
19 nov 2022
Accepted
08 jan 2023
First published
10 jan 2023

J. Mater. Chem. A, 2023,11, 2528-2543

Semi-quantitative determination of active sites in heterogeneous catalysts for photo/electrocatalysis

J. Ren, H. Chi, L. Tan, Y. Peng, G. Li, M. Meng-Jung Li, Y. Zhao and X. Duan, J. Mater. Chem. A, 2023, 11, 2528 DOI: 10.1039/D2TA09033C

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements