Issue 44, 2023

Dehydroabietane-type bifunctional organocatalysts in asymmetric synthesis: recent progress

Abstract

Dehydroabietane-type bifunctional organocatalysts derived from rosane-type diterpenes of dehydroabietic acid (DHAA) and dehydroabietylamine (DA) have been utilized in a wide variety of highly enantioselective reactions. Since one well-documented review exclusively reported on the development of terpene-derived bifunctional thioureas in asymmetric organocatalysis in 2013, fragmentary progress on the dehydroabietane-type bifunctional thioureas and squaramides has been mentioned in other reviews. In this mini-review, we systematically analyze and reorganize the published literature on dehydroabietane-type bifunctional organocatalysts in the recent decade according to the type of catalysts. Our aim is for this review to provide helpful research information and serve as a foundation for further design and application of rosin-based organocatalysts.

Graphical abstract: Dehydroabietane-type bifunctional organocatalysts in asymmetric synthesis: recent progress

Article information

Article type
Review Article
Submitted
03 okt 2023
Accepted
19 okt 2023
First published
24 okt 2023
This article is Open Access
Creative Commons BY-NC license

RSC Adv., 2023,13, 31047-31058

Dehydroabietane-type bifunctional organocatalysts in asymmetric synthesis: recent progress

Z. Zhang, S. Liu, H. Huang, Y. Xie, R. Huang, Y. Deng and N. Lin, RSC Adv., 2023, 13, 31047 DOI: 10.1039/D3RA06715G

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