Issue 1, 2023

Hierarchically ordered porous carbon with atomically dispersed cobalt for oxidative esterification of furfural

Abstract

Nitrogen-rich zeolitic imidazolate frameworks (ZIFs) are ideal precursors for the synthesis of metal single atoms anchored on N-doped carbon. However, the microporous structures of conventional ZIFs lead to low mass transfer efficiency and low metal utilization of their derivatives. Here, we construct a composite of Co single atoms anchored on nitrogen-doped carbon with a three-dimensional ordered macroporous structure (Co-SA/3DOM-NC) by two-step pyrolysis of ordered macro/microporous ZnCo-ZIF. Co-SA/3DOM-NC shows high activity in the oxidative esterification of furfural, achieving a 99% yield of methyl 2-furoate under mild reaction conditions, which is significantly superior to the microporous and the Co-nanoparticle counterparts. The high activity of Co-SA/3DOM-NC should be attributed to the CoN4 centers with high intrinsic activity and the ordered macroporous structure, promoting the mass transfer of reactants and accessibility of active sites.

Keywords: Heterogeneous catalysis; Hierarchical pores; Ordered macropore; Oxidative esterification reaction; Single-atom catalysts.

Graphical abstract: Hierarchically ordered porous carbon with atomically dispersed cobalt for oxidative esterification of furfural

Associated articles

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Article information

Article type
Paper
Submitted
14 nov 2022
Accepted
19 des 2022
First published
19 des 2022
This article is Open Access
Creative Commons BY-NC license

Ind. Chem. Mater., 2023,1, 106-116

Hierarchically ordered porous carbon with atomically dispersed cobalt for oxidative esterification of furfural

W. Yao, C. Hu, Y. Zhang, H. Li, F. Wang, K. Shen, L. Chen and Y. Li, Ind. Chem. Mater., 2023, 1, 106 DOI: 10.1039/D2IM00045H

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