Issue 43, 2023

Cyclo[n]carbons and catenanes from different perspectives: disentangling the molecular thread

Abstract

All-carbon atomic rings, cyclo[n]carbons, have recently attracted vivid attention of experimentalists and theoreticians. Among them, cyclo[18]carbon is the most studied system. In this paper, we summarize and review various properties of cyclo[n]carbons, emphasising the aspects of their aromaticity/antiaromaticity. In the first part, the trends in bonding patterns and selected aromaticity indices with the increasing size of the rings are discussed. In the second part we explore the properties of catenane models based on interlocked cyclo[18]carbon rings from different perspectives and investigate their behaviour under the action of external force using computational experiments.

Graphical abstract: Cyclo[n]carbons and catenanes from different perspectives: disentangling the molecular thread

Supplementary files

Article information

Article type
Perspective
Submitted
14 aug 2023
Accepted
17 okt 2023
First published
17 okt 2023

Phys. Chem. Chem. Phys., 2023,25, 29386-29403

Cyclo[n]carbons and catenanes from different perspectives: disentangling the molecular thread

S. Kozáková, N. Alharzali and I. Černušák, Phys. Chem. Chem. Phys., 2023, 25, 29386 DOI: 10.1039/D3CP03887D

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