Issue 28, 2022

A caged tris(2-pyridylmethyl)amine ligand equipped with a Ctriazole–H hydrogen bonding cavity

Abstract

A capped bioinspired ligand built from a tris(2-pyridyl-methyl)amine (TPA) unit and surmounted by a triazole-based intramolecular H-bonding secondary sphere was prepared. The resulting cage provides a well-defined cavity combining the hydrophobic nature with H-bonding properties. Its coordinating properties were explored using Zn(II) and Cu(II) metal ions.

Graphical abstract: A caged tris(2-pyridylmethyl)amine ligand equipped with a Ctriazole–H hydrogen bonding cavity

Supplementary files

Article information

Article type
Communication
Submitted
25 feb 2022
Accepted
18 apr 2022
First published
04 mai 2022
This article is Open Access
Creative Commons BY license

Dalton Trans., 2022,51, 10702-10706

A caged tris(2-pyridylmethyl)amine ligand equipped with a Ctriazole–H hydrogen bonding cavity

G. Qiu, D. Diao, L. Chaussy, S. Michaud-Chevallier, A. J. Simaan, P. Nava, A. Martinez and C. Colomban, Dalton Trans., 2022, 51, 10702 DOI: 10.1039/D2DT00607C

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