Issue 84, 2022

Crystalline phosphino(silyl)carbenes that readily form transition metal complexes

Abstract

Phosphino(silyl)carbenes are known for their ineptitude to form transition metal complexes. We describe the synthesis of phosphino(silyl)carbenes bearing N-heterocyclic imine groups and show that these isolable, crystalline carbenes readily form stable copper(I) and gold(I) complexes. The solid-state structures of the free carbenes and their transition metal complexes are reported.

Graphical abstract: Crystalline phosphino(silyl)carbenes that readily form transition metal complexes

Supplementary files

Article information

Article type
Communication
Submitted
02 aug 2022
Accepted
27 sep 2022
First published
28 sep 2022
This article is Open Access
Creative Commons BY license

Chem. Commun., 2022,58, 11831-11834

Crystalline phosphino(silyl)carbenes that readily form transition metal complexes

P. Löwe and F. Dielmann, Chem. Commun., 2022, 58, 11831 DOI: 10.1039/D2CC04321A

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