Issue 83, 2021

Access to adducts of parent iminoborane isomers, HBNH and NBH2, using frustrated Lewis pair chelation

Abstract

Adducts of the parent iminoborane isomers, HBNH and NBH2, have been prepared, each stabilized by the frustrated Lewis pair (FLP) chelate iPr2P(C6H4)BCy2 (PB). PB{HBNH} was accessed via dehydrohalogenation, while the corresponding isomer PB{NBH2} was obtained from the borylation of the formal nitrene-FLP complex PB{NH}.

Graphical abstract: Access to adducts of parent iminoborane isomers, HBNH and NBH2, using frustrated Lewis pair chelation

Supplementary files

Article information

Article type
Communication
Submitted
02 sep 2021
Accepted
22 sep 2021
First published
22 sep 2021

Chem. Commun., 2021,57, 10895-10898

Access to adducts of parent iminoborane isomers, HBNH and NBH2, using frustrated Lewis pair chelation

B. L. Frenette, A. A. Omaña, M. J. Ferguson, Y. Zhou and E. Rivard, Chem. Commun., 2021, 57, 10895 DOI: 10.1039/D1CC04923B

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