Issue 61, 2020
From the journal:

Chemical Communications

Steering alkyne homocoupling with on-surface synthesized metal–organic complexes†

Mohammed S. G. Mohammed, ORCID logo ab   Luciano Colazzo,‡ab   Aurelio Gallardo, ORCID logo cde   José A. Pomposo, ORCID logo bfg   Pavel Jelínekce  and  Dimas G. de Oteyza ORCID logo *abf  

* Corresponding authors

a Donostia International Physics Center (DIPC), 20018 San Sebastián, Spain
E-mail: d_g_oteyza@ehu.es

b Centro de Física de Materiales (CFM-MPC), CSIC-UPV/EHU, 20018 San Sebastián, Spain

c Institute of Physics, The Czech Academy of Sciences, 162 00 Prague, Czech Republic

d Faculty of Mathematics and Physics, Charles University, 180 00 Prague, Czech Republic

e RCPTM Palacký University Olomouc, 771 46 Olomouc, Czech Republic

f Ikerbasque, Basque Foundation for Science, 48013 Bilbao, Spain

g Departamento de Física de Materiales, Universidad del País Vasco (UPV/EHU), Apartado 1072, E-20800 San Sebastián, Spain

Abstract

We report a multi-step on-surface synthesis strategy. The first step consists in the surface-supported synthesis of metal–organic complexes, which are subsequently used to steer on-surface alkyne coupling reactions. In addition, we analyze and compare the electronic properties of the different coupling motifs obtained.

Graphical abstract: Steering alkyne homocoupling with on-surface synthesized metal–organic complexes

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Article information

DOI
https://doi.org/10.1039/D0CC03779F
Article type
Communication
Submitted
28 mai 2020
Accepted
22 jun 2020
First published
23 jun 2020

Chem. Commun., 2020,56, 8659-8662

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Steering alkyne homocoupling with on-surface synthesized metal–organic complexes

M. S. G. Mohammed, L. Colazzo, A. Gallardo, J. A. Pomposo, P. Jelínek and D. G. de Oteyza, Chem. Commun., 2020, 56, 8659 DOI: 10.1039/D0CC03779F

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