Issue 3, 2019

X-ray Raman optical activity of chiral molecules

Abstract

Resonant and off-resonant Raman Optical Activity signals in the X-ray regime (XROA) are predicted. XROA is a chiral-sensitive variant of the spontaneous Resonant Inelastic Scattering (RIXS) signal. Thanks to the highly localized nature of core excitations, these signals provide a direct probe of local chirality with high sensitivity to the molecular structure. We derive sum-over-states expressions for frequency domain XROA signals and apply them to tyrosine at the nitrogen and oxygen K-edges. Time-resolved extensions of ROA made possible by using additional pulses are briefly outlined.

Graphical abstract: X-ray Raman optical activity of chiral molecules

Supplementary files

Article information

Article type
Edge Article
Submitted
16 sep 2018
Accepted
30 okt 2018
First published
02 nov 2018
This article is Open Access

All publication charges for this article have been paid for by the Royal Society of Chemistry
Creative Commons BY-NC license

Chem. Sci., 2019,10, 898-908

X-ray Raman optical activity of chiral molecules

J. R. Rouxel, Y. Zhang and S. Mukamel, Chem. Sci., 2019, 10, 898 DOI: 10.1039/C8SC04120B

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