Issue 60, 2019

Mechanism and regioselectivity of the anionic oxidative rearrangement of 1,3-diketones towards all-carbon quaternary carboxylates

Abstract

The oxidative rearrangement of 1,3-diketones is an underexplored alternative to enolate chemistry in the synthesis of all-carbon quaternary carboxylates. The mechanistic investigation of this reaction has resulted in a mild base mediated protocol, whose regioselectivity has been studied in challenging acyclic substrates.

Graphical abstract: Mechanism and regioselectivity of the anionic oxidative rearrangement of 1,3-diketones towards all-carbon quaternary carboxylates

Supplementary files

Article information

Article type
Communication
Submitted
30 apr 2019
Accepted
29 mai 2019
First published
03 jun 2019
This article is Open Access
Creative Commons BY-NC license

Chem. Commun., 2019,55, 8844-8847

Mechanism and regioselectivity of the anionic oxidative rearrangement of 1,3-diketones towards all-carbon quaternary carboxylates

E. Bratt, S. Suárez-Pantiga, M. J. Johansson and A. Mendoza, Chem. Commun., 2019, 55, 8844 DOI: 10.1039/C9CC03331A

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