Issue 17, 2018

Metal-free deoxygenative sulfonylation of quinoline N-oxides with sodium sulfinates via a dual radical coupling process

Abstract

The first example of a metal- and reductant-free deoxygenative sulfonylation of quinoline N-oxides with sodium sulfinates via a dual radical coupling process is reported. In this reaction, sodium sulfinates play dual roles of a sulfonylation reagent and activating agent. This procedure is expected to complement the current methods for the radical reaction of quinoline N-oxides.

Graphical abstract: Metal-free deoxygenative sulfonylation of quinoline N-oxides with sodium sulfinates via a dual radical coupling process

Supplementary files

Article information

Article type
Research Article
Submitted
03 jul 2018
Accepted
27 jul 2018
First published
07 aug 2018

Org. Chem. Front., 2018,5, 2604-2609

Metal-free deoxygenative sulfonylation of quinoline N-oxides with sodium sulfinates via a dual radical coupling process

L. Xie, S. Peng, F. Liu, G. Chen, W. Xia, X. Yu, W. Li, Z. Cao and W. He, Org. Chem. Front., 2018, 5, 2604 DOI: 10.1039/C8QO00661J

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