Issue 36, 2018

Synthesis and photophysical properties of imine borane adducts towards vapochromic materials

Abstract

A series of alkynyl aryl conjugated aldehydes and imines were prepared and their adducts with various Lewis acidic boranes have been studied via NMR, absorption, and luminescence spectroscopies in solution. The imine-B(C6F5)3 adduct showed remarkable solution stability, and was then trialled in vapochromism experiments using simple impregnated paper strips to examine the fluorescence responses.

Graphical abstract: Synthesis and photophysical properties of imine borane adducts towards vapochromic materials

Supplementary files

Article information

Article type
Communication
Submitted
24 jul 2018
Accepted
08 aug 2018
First published
23 aug 2018

Dalton Trans., 2018,47, 12656-12660

Synthesis and photophysical properties of imine borane adducts towards vapochromic materials

Y. Soltani, S. J. Adams, J. Börger, L. C. Wilkins, P. D. Newman, S. J. A. Pope and R. L. Melen, Dalton Trans., 2018, 47, 12656 DOI: 10.1039/C8DT03019G

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