Issue 51, 2018

Yet again, new compounds found in systems with known binary phase diagrams. Synthesis, crystal and electronic structure of Nd3Bi7 and Sm3Bi7

Abstract

The binary bismuthides Nd3Bi7 and Sm3Bi7 were synthesized and structurally characterized for the first time. The results from the calorimetric analysis show that both compounds are stable only up to about 500 °C, which may explain why they were overlooked during the original assessment of the corresponding phase diagrams.

Graphical abstract: Yet again, new compounds found in systems with known binary phase diagrams. Synthesis, crystal and electronic structure of Nd3Bi7 and Sm3Bi7

Supplementary files

Article information

Article type
Communication
Submitted
03 apr 2018
Accepted
02 jun 2018
First published
04 jun 2018

Chem. Commun., 2018,54, 7089-7092

Author version available

Yet again, new compounds found in systems with known binary phase diagrams. Synthesis, crystal and electronic structure of Nd3Bi7 and Sm3Bi7

A. Ovchinnikov, J. P. A. Makongo and S. Bobev, Chem. Commun., 2018, 54, 7089 DOI: 10.1039/C8CC02563K

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