Issue 82, 2017

A rational molecular design of triazine-containing alkynylplatinum(ii) terpyridine complexes and the formation of helical ribbons via Pt⋯Pt, π–π stacking and hydrophobic–hydrophobic interactions

Abstract

The self-assembly of triazine-containing alkynylplatinum(II) terpyridine complexes has revealed the formation of sophisticated helical ribbons. Fine control of the morphological transition from plates to helical structures has been demonstrated through an interplay of the bent molecular structure and Pt⋯Pt, π−π stacking and hydrophobic–hydrophobic interactions.

Graphical abstract: A rational molecular design of triazine-containing alkynylplatinum(ii) terpyridine complexes and the formation of helical ribbons via Pt⋯Pt, π–π stacking and hydrophobic–hydrophobic interactions

Supplementary files

Article information

Article type
Communication
Submitted
11 aug 2017
Accepted
22 sep 2017
First published
02 okt 2017

Chem. Commun., 2017,53, 11349-11352

A rational molecular design of triazine-containing alkynylplatinum(II) terpyridine complexes and the formation of helical ribbons via Pt⋯Pt, π–π stacking and hydrophobic–hydrophobic interactions

H. L. Fu, S. Y. Leung and V. W. Yam, Chem. Commun., 2017, 53, 11349 DOI: 10.1039/C7CC06293A

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