Issue 5, 2010

Bio-supramolecular photochirogenesis with molecular chaperone: enantiodifferentiating photocyclodimerization of 2-anthracenecarboxylate mediated by prefoldin

Abstract

Photocyclodimerization of 2-anthracenecarboxylate mediated by molecular chaperone protein was performed for the first time to afford chiral syn-head-to-tail and anti-head-to-head dimers (2 and 3) in 10% and 16% enantiomeric excess, respectively, with enhanced yields of sterically and electrostatically less-favored head-to-head dimers (3 and 4).

Graphical abstract: Bio-supramolecular photochirogenesis with molecular chaperone: enantiodifferentiating photocyclodimerization of 2-anthracenecarboxylate mediated by prefoldin

Article information

Article type
Paper
Submitted
04 des 2009
Accepted
05 feb 2010
First published
02 mar 2010

Photochem. Photobiol. Sci., 2010,9, 655-660

Bio-supramolecular photochirogenesis with molecular chaperone: enantiodifferentiating photocyclodimerization of 2-anthracenecarboxylate mediated by prefoldin

K. Bando, T. Zako, M. Sakono, M. Maeda, T. Wada, M. Nishijima, G. Fukuhara, C. Yang, T. Mori, T. C. S. Pace, C. Bohne and Y. Inoue, Photochem. Photobiol. Sci., 2010, 9, 655 DOI: 10.1039/B9PP00186G

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