Issue 72, 2004

Phenylamines as building blocks to layered inorganic–organic structures

Abstract

Five inorganic–organic layered composites have been prepared and characterised. Copper(II) chloride and lead(II) chloride compounds with 1,4-phenylenediamine and benzidine have a 1∶1 inorganic∶organic layer structure. The copper(II) chloride structure with p-biphenylamine is a 1∶2 inorganic∶organic layer structure; this compound undergoes an order–disorder transition at ca. 200 K. Crystallisation of benzidine in the presence of lead (II) chloride or cobalt(II) chloride at elevated temperature produced the chloride salt of benzidine.

Graphical abstract: Phenylamines as building blocks to layered inorganic–organic structures

Article information

Article type
Paper
Submitted
04 mai 2004
Accepted
03 jun 2004
First published
17 sep 2004

CrystEngComm, 2004,6, 438-442

Phenylamines as building blocks to layered inorganic–organic structures

S. A. Bourne and Z. Mangombo, CrystEngComm, 2004, 6, 438 DOI: 10.1039/B406671E

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