Issue 11, 2023

Understanding supercapacitive performance of a N-doped vanadium carbide/carbon composite as an anode material in an all pseudocapacitive asymmetric cell

Abstract

Pseudocapacitive asymmetric supercapacitors (ASCs) have captivated huge attention in electrochemical energy storage applications owing to their wide operating voltage window and high energy/power densities as compared to carbon-based double layer capacitors. Yet it is challenging to achieve electrochemical performance compatibility between negative and positive electrodes for optimum ASC performance. Herein, we have fabricated an all pseudocapacitive asymmetric supercapacitor using a N-doped V4C3/C nano-heterostructure with a porous layered structure as the negative electrode and a VO2/VSe2 hybrid composite with flower-like morphology as the positive electrode material. A N-doped V4C3/C nano heterostructure is realized using a novel in situ reduction/carbonization method with V2O5 and dicyandiamide as precursors. The porous layered structure thus produced provides abundant reaction sites and facilitates fast ion transport, resulting in a specific capacitance of 118 F g−1 at a current density of 0.75 A g−1 with an outstanding rate capability up to 20 A g−1 current density and good cycling stability after 10 000 cycles. The partially selenized vanadium oxide (VO2/VSe2 hybrid) positive electrode also exhibits a specific capacitance of 108.9 F g−1 at 0.25 A g−1 current density, along with an ultrahigh cycling stability of 97% after 10 000 cycles. The assembled N-doped V4C3/C//VO2/VSe2 ASC displays a 1.8 V stable voltage window in 1 M sodium sulfate aqueous electrolyte and can deliver an energy density of 21.4 W h kg−1 and a power density of 4.5 kW kg−1, which surpasses those of many aqueous-based symmetric and asymmetric supercapacitors, and thus substantiates the prospect of vanadium-based materials for high-performance electrochemical energy storage systems.

Graphical abstract: Understanding supercapacitive performance of a N-doped vanadium carbide/carbon composite as an anode material in an all pseudocapacitive asymmetric cell

Supplementary files

Article information

Article type
Paper
Submitted
24 jan 2023
Accepted
19 apr 2023
First published
20 apr 2023

Sustainable Energy Fuels, 2023,7, 2613-2626

Understanding supercapacitive performance of a N-doped vanadium carbide/carbon composite as an anode material in an all pseudocapacitive asymmetric cell

H. K. Rathore, M. Hariram, M. K. Ganesha, A. K. Singh, D. Das, M. Kumar, K. Awasthi and D. Sarkar, Sustainable Energy Fuels, 2023, 7, 2613 DOI: 10.1039/D3SE00092C

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