Issue 48, 2023

Circularly polarized luminescence and nonlinear optical harmonic generation based on chiral zinc halides

Abstract

Chiral hybrid metal halides have grabbed extensive attention in linear and nonlinear chiroptics. Herein, 0D chiral zinc halides, (R-/S-2-MP)ZnCl4, have been fabricated, which demonstrate high efficiency second-order nonlinear optical responses. Incorporating Sb3+ into the chiral zinc halide matrix triggers the circularly polarized luminescence effectively with a balance between quantum yield and luminescence dissymmetry factor.

Graphical abstract: Circularly polarized luminescence and nonlinear optical harmonic generation based on chiral zinc halides

  • This article is part of the themed collection: Perovskites

Supplementary files

Article information

Article type
Communication
Submitted
25 mar 2023
Accepted
23 mai 2023
First published
23 mai 2023

Chem. Commun., 2023,59, 7447-7450

Circularly polarized luminescence and nonlinear optical harmonic generation based on chiral zinc halides

X. Han, P. Cheng, W. Han, R. Shi, J. Guan, G. Li and J. Xu, Chem. Commun., 2023, 59, 7447 DOI: 10.1039/D3CC01461D

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