Issue 14, 2021

C–H hetero-functionalization of arenes through palladacyclopentane-type intermediates

Abstract

Recent years have witnessed palladium-catalyzed C–H activation emerging as a versatile strategy for the construction of valuable scaffolds. Palladacyclopentane-type intermediates, usually created by C–H activation from an aryl-Pd(II) precursor, provide opportunities for subsequent C–H hetero-functionalizations and have therefore received much attention in organic synthesis. In this review article, we summarise recent advances in the C–H hetero-functionalization of arenes through palladacyclopentane-type intermediates over the past decade.

Graphical abstract: C–H hetero-functionalization of arenes through palladacyclopentane-type intermediates

Article information

Article type
Review Article
Submitted
02 nov 2020
Accepted
02 apr 2021
First published
02 apr 2021

Org. Chem. Front., 2021,8, 3883-3914

C–H hetero-functionalization of arenes through palladacyclopentane-type intermediates

L. Cao, Y. Hua, H. Cheng and Q. Zhou, Org. Chem. Front., 2021, 8, 3883 DOI: 10.1039/D0QO01350A

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