Issue 44, 2020

Probing the versatility of metallo-electro hybrid catalysis: enabling access towards facile C–N bond formation

Abstract

The development of versatile and mild methodologies for C–N bond construction has always been a hot topic of interest in synthetic organic chemistry. In recent years, electrochemistry has emerged as a promising green and sustainable environmentally benign approach to carry out these transformations under mild conditions utilizing electrons as oxidizing/reducing agents. The current state-of-the-art in combining electrocatalysis with transition metal catalysis has gained significant attention. This hybrid synthetic methodology has increasingly become a common tool and offers many potential advantages compared to direct electrolysis. This review comprehensively highlights recent developments in the merging of transition metal catalysis in electro-organic synthesis for the facile construction of C–N bonds. In this review major emphasis is given to mechanistic investigations and their synthetic applications of this hybrid catalysis.

Graphical abstract: Probing the versatility of metallo-electro hybrid catalysis: enabling access towards facile C–N bond formation

Article information

Article type
Review Article
Submitted
10 sep 2020
Accepted
16 okt 2020
First published
16 okt 2020

Org. Biomol. Chem., 2020,18, 8994-9017

Probing the versatility of metallo-electro hybrid catalysis: enabling access towards facile C–N bond formation

P. P. Sen, N. Dagar, S. Singh, V. J. Roy, V. Pathania and S. Raha Roy, Org. Biomol. Chem., 2020, 18, 8994 DOI: 10.1039/D0OB01874K

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