Issue 37, 2020

FLP-catalysis meets hydrogen-bond activation

Abstract

The potential of two chiral amidines and three non-chiral boranes in the metal-free hydrogen activation was explored. The resulting chiral amidiunium borohydride salts were investigated in asymmetric hydrogenation reactions of ketimines, activated double bonds and dehydro amioacid esters.

Graphical abstract: FLP-catalysis meets hydrogen-bond activation

Supplementary files

Article information

Article type
Communication
Submitted
20 jul 2020
Accepted
10 sep 2020
First published
10 sep 2020

Org. Biomol. Chem., 2020,18, 7321-7325

FLP-catalysis meets hydrogen-bond activation

N. A. Sitte, L. Köring, P. W. Roesky and J. Paradies, Org. Biomol. Chem., 2020, 18, 7321 DOI: 10.1039/D0OB01492C

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