Issue 9, 2018

Silver-catalyzed ring-opening difluoromethylthiolation/trifluoromethylthiolation of cycloalkanols with PhSO2SCF2H or PhSO2SCF3

Abstract

A silver-catalyzed ring-opening difluoromethylthiolation/trifluoromethylthiolation of cycloalkanols including cyclopropanols, cyclobutanols, cyclopentanols, cyclohexanols and cycloheptanols was described. A variety of common functional groups such as fluoride, chloride, bromide, iodide, trifluoromethyl, cyano and ester groups were compatible.

Graphical abstract: Silver-catalyzed ring-opening difluoromethylthiolation/trifluoromethylthiolation of cycloalkanols with PhSO2SCF2H or PhSO2SCF3

Supplementary files

Article information

Article type
Research Article
Submitted
01 feb 2018
Accepted
05 mar 2018
First published
06 mar 2018

Org. Chem. Front., 2018,5, 1462-1465

Silver-catalyzed ring-opening difluoromethylthiolation/trifluoromethylthiolation of cycloalkanols with PhSO2SCF2H or PhSO2SCF3

B. Xu, D. Wang, Y. Hu and Q. Shen, Org. Chem. Front., 2018, 5, 1462 DOI: 10.1039/C8QO00115D

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