Issue 74, 2018

Photochemical and electrochemical hydrogen evolution reactivity of lanthanide-functionalized polyoxotungstates

Abstract

The first example of hydrogen evolution reactivity (HER) of lanthanide-functionalized Keggin-based polyoxotungstates under photochemical and electrochemical conditions is reported. The HER activity under homogeneous, visible light-driven conditions and under heterogeneous, electrochemical conditions depends on the type of lanthanide functionalization, so that a new class of model HER catalysts for systematic reactivity studies is now accessible.

Graphical abstract: Photochemical and electrochemical hydrogen evolution reactivity of lanthanide-functionalized polyoxotungstates

Supplementary files

Article information

Article type
Communication
Submitted
03 aug 2018
Accepted
23 aug 2018
First published
23 aug 2018

Chem. Commun., 2018,54, 10427-10430

Photochemical and electrochemical hydrogen evolution reactivity of lanthanide-functionalized polyoxotungstates

M. Arab Fashapoyeh, M. Mirzaei, H. Eshtiagh-Hosseini, A. Rajagopal, M. Lechner, R. Liu and C. Streb, Chem. Commun., 2018, 54, 10427 DOI: 10.1039/C8CC06334F

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