Issue 10, 2013
From the journal:

Catalysis Science & Technology

Nanocrystalline magnesium oxide-stabilized palladium(0): the Heck reaction of heteroaryl bromides in the absence of additional ligands and base†

Mannepalli Lakshmi Kantam,*a   Police Vishnuvardhan Redddy,a   Pottabathula Srinivas,a   Akula Venugopal,a   Suresh Bhargavab  and  Yuta Nishinac  

* Corresponding authors

a I & PC Division, CSIR-Indian Institute of Chemical Technology, Hyderabad – 500 607, India
E-mail: mlakshmi@iict.res.in
Fax: +91-40-27193510
Tel: +91-40-27193510

b Advanced Materials & Industrial Chemistry Group, School of Applied Sciences, RMIT University, Melbourne, Australia

c Research Core for Interdisciplinary Sciences, Okayama University, Tsushima, Kita-ku, Okayama 700-8530, Japan

Abstract

An efficient and user-friendly protocol has been realized for the Heck reaction of heteroaryl bromides by using a reusable nanocrystalline magnesium oxide-stabilized palladium(0) catalyst without the aid of additional ligands and base. Dimethylamine generated under in situ conditions by the decomposition of DMF serves as the base in this reaction. The catalyst was reused with consistent activity up to four cycles.

Graphical abstract: Nanocrystalline magnesium oxide-stabilized palladium(0): the Heck reaction of heteroaryl bromides in the absence of additional ligands and base

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/C3CY00404J
Article type
Communication
Submitted
12 jun 2013
Accepted
03 jul 2013
First published
04 jul 2013

Catal. Sci. Technol., 2013,3, 2550-2554

Permissions

Request permissions

Nanocrystalline magnesium oxide-stabilized palladium(0): the Heck reaction of heteroaryl bromides in the absence of additional ligands and base

M. L. Kantam, P. V. Redddy, P. Srinivas, A. Venugopal, S. Bhargava and Y. Nishina, Catal. Sci. Technol., 2013, 3, 2550 DOI: 10.1039/C3CY00404J

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements