This work, a catalytic system of transfer hydrogenation of pyrazole ligand with Mn is introduced, which realizes the efficient transfer hydrogenation of various alcohols through dehydrogenation halogenation pre-activation.
Commercially available MnBr(CO)5 was found to be a remarkable catalyst for olefin hydrosilylation reactions using a wide range of olefins and silanes. This system tolerates unpurified substrates and can be used in green solvents under ambient air.
The commercially available, inexpensive and air-stable manganese catalyst MnBr(CO)5 has proven to be an excellent catalyst for the reduction of a wide variety of sulfoxides to the corresponding sulfides in excellent yields and good chemoselectivity.
This review highlights the transformative roles of ionic liquids (ILs) in organic synthesis, serving as solvents, additives, promoters, electrolytes and catalysts for the synthesis and functionalization of molecules through C–H activation reactions.
A highly efficient and selective catalytic method for the methoxymethylation of primary amides with the liberation of dihydrogen under Mn(I) catalysis is reported.