Nickel catalyzed cross-coupling reaction of 2-methylthiobenzo[d]thiazole with aryl/alkenyl aluminum to obtain various derivatives of 2-(hetero)aryl/2-alkenyl substituted benzo[d]thiazoles in 31–94% isolated yields.
The present study involves the synthesis of a new series of α-aminophosphonate derivatives in good yields with a simple workup via the Kabachnik–Fields reaction using lithium perchlorate (LiClO4) as a catalyst to facilitate the reaction.
The presence of an ortho-linked substituent in pyrene can lead to steric hindrance on one side of the pyrene plane, which prevents the formation of undesired interactions and promotes the selective formation of dimers in a desired orientation.
Some novel benzo[d]thiazole–1,2,3-triazole hybrid compounds with benzamide and/or benzoate tethers were synthesized as EGFR-dependent signaling inhibitors against breast cancer.
This review highlights the developments in stimuli-fluorochromic π-conjugated solids beyond organometallic and organic light-responsive compounds, addressing the design strategies, mechanisms, limitations, challenges, and opportunities.