Visible light-enabled alkylation of enol acetates with alkylboronic acids for the synthesis of α-alkyl ketones

Yunpu Li, Zhenqiang Ma, Xiaopei Liu, Zhongxian Li, Fengqian Zhao and Junliang Wu

Org. Chem. Front., 2023, 10, 1710
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Straightforward α-allylation of carbonyl compounds with alkenes via α-carbonyl radical intermediates

Sien Liu, Yanjing Liao, Hongyi Li, Biping Xu, Xiaofeng Zhang, Yaping Shang and Weiping Su

Org. Chem. Front., 2024, 11, 2502
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Catalytic α-C–H functionalization of carbonyl compounds via SET-induced formation of α-carbonyl radicals

Anupam Kumar Singh and Sukalyan Bhadra

Chem. Commun., 2025, 61, 14059
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Di-tert-butyl peroxide as an effective two-carbon unit in oxidative radical cyclization toward 7-methylazolo[1,5-a]pyrimidines

Qinghe Gao, Zhenhua Sun, Manman Wu, Yimei Guo, Xinya Han, Jufen Yan, Minh Ngoc Ha, Quynh Mai Le and Yongtao Xu

Org. Chem. Front., 2022, 9, 3050
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Photoredox-catalyzed 1,2-oxo-alkylation of vinyl arenes with 1,3-diketones: an approach to 1,4-dicarbonyls via C–C activation

Pushbaraj Palani, Ajithkumar Arumugam, Dineshkumar Raja, Kesavan Muthu and Gopal Chandru Senadi

Chem. Commun., 2023, 59, 11433
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Magnetic MoS2 efficient heterogeneous photocatalyst for the α-methoxymethylation and aminomethylation of aromatic ketones

Ya-Meng Wang, Wen-Jing Li, Miao-Miao Wang, Mo Zhang and Zhan-Hui Zhang

Catal. Sci. Technol., 2023, 13, 665
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Copper catalyzed C(sp3)–H/C(sp3)–H cross-coupling of arylacetic acid equivalents with methylarenes via α-carbonyl radicals

Anupam Kumar Singh, Ajijur Rahaman, Upendra Kumar Brijmohan Patel, Tulsi R. Patel, Surjit Bhai, Bishwajit Ganguly and Sukalyan Bhadra

Chem. Commun., 2025, 61, 2941
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C-centered radical-initiated cyclization by directed C(sp3)–H oxidative functionalization

Jiao-Zhe Li, Lan Mei, Xuan-Chi Yu, Ling-Tao Wang, Xue-Er Cai, Ting Li and Wen-Ting Wei

Org. Chem. Front., 2022, 9, 5726
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Radical Cascade Cyclization Involving C(sp3)—H Functionalization of Unactivated Cycloalkanes

Rongnan Yi, Jiaozhe Li, Dongkai Wang and Wenting Wei

Chinese Journal of Organic Chemistry, 2022, 42, 4111
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Direct Synthesis of K-Region Functionalized Polycyclic Aromatic Hydrocarbons via Twofold Intramolecular C–H/C–H Arylation

Hao Li, Dandan Lu, Bai-Yang Qian, Jianbin Lin and Hui-Jun Zhang

Org. Lett., 2024, 26, 11140
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Methyl Ketones as Alkyl Halide Surrogates: A Deacylative Halogenation Approach for Strategic Functional Group Conversions

Zining Zhang, Qi Zhu, Daniel Pyle, Xukai Zhou and Guangbin Dong

J. Am. Chem. Soc., 2023, 145, 21096
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Research Progress of Carbonyl α-Position Amination

Wenqian Wu, Chunxia Chen, Jinsong Peng and Zhanyu Li

Chinese Journal of Organic Chemistry, 2023, 43, 2743
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Investigations into Intramolecular Cerium‐ and Manganese‐Catalyzed Aerobic Coupling of β‐Oxoesters with Styryl Moieties

Julian Friedrich, Marc Schmidtmann and Jens Christoffers

Eur J Org Chem, 2025, 28
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Visible Light‐Promoted Fluorescein/Ni‐Catalyzed Synthesis of Bis‐(β‐Dicarbonyls) using Olefins as a Methylene Bridge Synthon

Pushbaraj Palani, Ajithkumar Arumugam, Mageshwari Anandan, Venkatramaiah Nutalapati, Karthick Govindan, Wei‐Yu Lin and Gopal Chandru Senadi

Asian J Org Chem, 2022, 11
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Mild Hydroalkylation of Terminal Olefins Via Decatungstate/Thiol Cooperative Photocatalysis

Austin J. Moser, Paige E. Sutter, Alex M. Chavez, Sebastian A. Cruz and Julian G. West

Org. Lett., 2025, 27, 4529
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Deoxygenative cross-coupling of aryl ketones with (Hetero)arenes mediated by a TiCl4/Ammonia borane system

Yong-jun Zang, Shi-jie Zhou, Chen Qian, Qi-lin Xu, Guo-si Li, Xing Li and Fu-cheng Zhu

Tetrahedron, 2024, 163, 134147
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Photoredox Catalytic Approach for Difluoroallylation of Electron-Deficient sp3 C–H Bonds

Xin-Lu Fan, Zi-Yan Wang, Wei Shi, Zi-Jun Luo, Xuefei Zhao and Xu-Hong Hu

Org. Lett., 2025, 27, 8607
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Direct Assembly of Polysubstituted Furans with Dimethyl Sulfoxide as a Multipurpose Precursor via β‐C(sp3)−H Functionalization of Saturated Ketones

Hai‐Lu Lin, Yu‐Tao Cheng, Feng Yang, Yu‐Feng Liu and Guo‐Ping Yang

Adv Synth Catal, 2022, 364, 3789
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Merging Photoinduced Electron Transfer with Hydrogen Atom Transfer: Formal β-C(sp3)–H Pyridination of Carbonyls

Jian Li, Jun Xu, Binbin Chen, Qing Pang, Jiabin Shen, Kai Wang and Pengfei Zhang

J. Org. Chem., 2025, 90, 1354
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Tuning the reactivity of benzylic radicals by virtue of the presence of an acid/ester functional group at the benzylic carbon

Upma Gulati, Anjali Gupta and Joydev K. Laha

Tetrahedron, 2026, 191, 135086
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Mechanisms of C(sp3)-H Functionalization of Acetonitrile or Acetone with Alkynes: A DFT Investigation

Bin Chen, Tian-Tian Feng, Da-Gang Zhou and Li-Jun Yang

J. Chem. Inf. Model., 2025, 65, 1953
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One‐Pot Reactions of Ynones with Isothiocyanates for Accessing 2‐Aminothiophenone and Indole‐Fused/Indole‐Substituted Thiophenone Derivatives

Zefeng Jin, Cuiying Li, Guodong Shen, Honglan Kang and Xin Lv

Adv Synth Catal, 2024, 366, 5151
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Visible-light-mediated oxidant-free tandem acylmethylation/ipso-spirocyclization of N-arylpropiolamides: Access to 3-acylmethyl azaspiro[4,5]trienones

Binfeng Zhu, Guokai Li, Mingzhu Li, Deyu Bao, Jingchao Chen, Devendar Ponnam and Baomin Fan

Molecular Catalysis, 2025, 582, 115120
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Radical Cyclization of N-Methacryloyl-2-arylbenzoimidazoles with Nitriles, Ketones, and tert-Butyl Nitrite under Mild Conditions

Li-Lin Jiang, Ling-Tao Wang, Hui Qiu, Fa-Liang Liu, Xun-Jie Huang, Ting-Ting Cao, Guo-Ping Ge, Yi-Lin Liu and Wen-Ting Wei

Synthesis, 2022, 54, 5233
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Breast cancer cell targeting of L-leucine-PLGA conjugated hybrid solid lipid nanoparticles of betulin via L-amino acid transport system-1

Shilpa Amit Gajbhiye and Moreshwar P. Patil

Journal of Drug Targeting, 2025, 33, 1432
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