Models of the iron-only hydrogenase enzyme: structure, electrochemistry and catalytic activity of Fe2(CO)3(μ-dithiolate)(μ,κ1,κ2-triphos)

David G. Unwin, Shishir Ghosh, Faith Ridley, Michael G. Richmond, Katherine B. Holt and Graeme Hogarth

Dalton Trans., 2019, 48, 6174
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Models of the iron-only hydrogenase: a comparison of chelate and bridge isomers of Fe2(CO)4{Ph2PN(R)PPh2}(μ-pdt) as proton-reduction catalysts

Shishir Ghosh, Graeme Hogarth, Nathan Hollingsworth, Katherine B. Holt, Idris Richards, Michael G. Richmond, Ben E. Sanchez and David Unwin

Dalton Trans., 2013, 42, 6775
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Triiron clusters derived from dinuclear complexes related to the active site of [Fe–Fe] hydrogenases: steric effect of the dithiolate bridge on redox properties, a DFT analysis

Ahmad Hobballah, Federica Arrigoni, Catherine Elleouet, Claudio Greco, Maxime Laurans, François Y. Pétillon and Philippe Schollhammer

Inorg. Chem. Front., 2021, 8, 3659
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[FeFe]-Hydrogenases: maturation and reactivity of enzymatic systems and overview of biomimetic models

Julian T. Kleinhaus, Florian Wittkamp, Shanika Yadav, Daniel Siegmund and Ulf-Peter Apfel

Chem. Soc. Rev., 2021, 50, 1668
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Mixed-valence [FeIFeII] hydrogenase active site model complexes stabilized by a bidentate carborane bis-phosphine ligand

Michael Karnahl, Stefanie Tschierlei, Özlen F. Erdem, Sonja Pullen, Marie-Pierre Santoni, Edward J. Reijerse, Wolfgang Lubitz and Sascha Ott

Dalton Trans., 2012, 41, 12468
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Coordination and conformational isomers in mononuclear iron complexes with pertinence to the [FeFe] hydrogenase active site

Andreas Orthaber, Michael Karnahl, Stefanie Tschierlei, Daniel Streich, Matthias Stein and Sascha Ott

Dalton Trans., 2014, 43, 4537
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Protonation and electrochemical properties of a bisphosphide diiron hexacarbonyl complex bearing amino groups on the phosphide bridge

Takehiko Shimamura, Yuki Maeno, Kazuyuki Kubo, Shoko Kume, Claudio Greco and Tsutomu Mizuta

Dalton Trans., 2019, 48, 16595
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Bio-inspired hydrogenase models: mixed-valence triion complexes as proton reduction catalysts

Shishir Ghosh, Graeme Hogarth, Katherine B. Holt, Shariff E. Kabir, Ahibur Rahaman and David G. Unwin

Chem. Commun., 2011, 47, 11222
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Synthesis, Characterization and Electrochemical Reductive Properties of Complexes [Fe2(CO)4(κ2‐PPh2NR2)(µ‐dithiolato)] Related to the H‐Cluster of [FeFe]‐H2ases

Ahmad Hobballah, Sondes Lounissi, Rachid Motei, Catherine Elleouet, François Y. Pétillon and Philippe Schollhammer

Eur J Inorg Chem, 2021, 2021, 205
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Structural and spectroscopic characterization of tetranuclear iron complexes containing a bridge

Michael Karnahl, Andreas Orthaber, Stefanie Tschierlei, Loganathan Nagarajan and Sascha Ott

Journal of Coordination Chemistry, 2012, 65, 2713
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Facile P−C/C−H Bond‐Cleavage Reactivity of Nickel Bis(diphosphine) Complexes

Shaoguang Zhang, Haixia Li, Aaron M. Appel, Michael B. Hall and R. Morris Bullock

Chemistry A European J, 2016, 22, 9493
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Structural and HER studies of diphosphine-monothiolate complexes [Fe2(CO)4(μ-naphthalene-2-thiolate)2(μ-dppe)] and [Fe2(CO)4(μ-naphthalene-2-thiolate)2(μ-DPEPhos)]

Hemlata Faujdar, Anke Spannenberg and Sandeep Kaur-Ghumaan

Inorganica Chimica Acta, 2020, 501, 119227
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RETRACTED: Substitution reactions of diiron dithiolate complexes with phosphine or isocyanide ligands

Xu-Feng Liu

Journal of Organometallic Chemistry, 2014, 750, 117
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Bioinspired Hydrogenase Models: The Mixed-Valence Triiron Complex [Fe3(CO)7(μ-edt)2] and Phosphine Derivatives [Fe3(CO)7–x(PPh3)x(μ-edt)2] (x = 1, 2) and [Fe3(CO)5(κ2-diphosphine)(μ-edt)2] as Proton Reduction Catalysts

Ahibur Rahaman, Shishir Ghosh, David G. Unwin, Sucharita Basak-Modi, Katherine B. Holt, Shariff E. Kabir, Ebbe Nordlander, Michael G. Richmond and Graeme Hogarth

Organometallics, 2014, 33, 1356
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Dynamics and Coordination of a P2N2 Ligand – from Twisted Conformation to Chelation

Benedict J. Elvers, Christian Fischer and Carola Schulzke

Chemistry A European J, 2024, 30
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Solution-phase photochemistry of a [FeFe]hydrogenase model compound: Evidence of photoinduced isomerisation

Rafal Kania, Pim W. J. M. Frederix, Joseph A. Wright, Rein V. Ulijn, Christopher J. Pickett and Neil T. Hunt

The Journal of Chemical Physics, 2012, 136
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PNP-Chelated and -Bridged Diiron Dithiolate Complexes Fe2(μ-pdt)(CO)4{(Ph2P)2NR} Together with Related Monophosphine Complexes for the [2Fe]H Subsite of [FeFe]-Hydrogenases: Preparation, Structure, and Electrocatalysis

Pei-Hua Zhao, Zhong-Yi Ma, Meng-Yuan Hu, Jiao He, Yan-Zhong Wang, Xing-Bin Jing, Hui-Yu Chen, Zheng Wang and Yu-Long Li

Organometallics, 2018, 37, 1280
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The Hydrogen Evolution Reaction: Using Molecular Design in Transition Metal Complexes to Control Catalytic Microenvironments on Electrode Surfaces

Logan Trowbridge and Peter E. Sues

ChemCatChem, 2024
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An unexpected leading role for [Fe2(CO)6(μ-pdt)] in our understanding of [FeFe]-H2ases and the search for clean hydrogen production

Graeme Hogarth

Coordination Chemistry Reviews, 2023, 490, 215174
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Phosphine-substituted diiron 1,2-dithiolate complexes as the models for the active site of [FeFe]-hydrogenases

Lin Yan, Jiao He, Xu-Feng Liu, Yu-Long Li, Zhong-Qing Jiang and Hong-Ke Wu

Journal of Coordination Chemistry, 2019, 72, 2531
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Synthesis, Protonation, and Reduction of Ruthenium–Peroxo Complexes with Pendent Nitrogen Bases

Tristan A. Tronic, Werner Kaminsky, Michael K. Coggins and James M. Mayer

Inorg. Chem., 2012, 51, 10916
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Biomimetics of the [FeFe]-hydrogenase enzyme: Identification of kinetically favoured apical-basal [Fe2(CO)4(μ-H){κ2-Ph2PC(Me2)PPh2}(μ-pdt)]+ as a proton-reduction catalyst

Shishir Ghosh, Ben E. Sanchez, Idris Richards, Mohammed N. Haque, Katherine B. Holt, Michael G. Richmond and Graeme Hogarth

Journal of Organometallic Chemistry, 2016, 812, 247
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Molecular Catalysts with Diphosphine Ligands Containing Pendant Amines

Eric S. Wiedner, Aaron M. Appel, Simone Raugei, Wendy J. Shaw and R. Morris Bullock

Chem. Rev., 2022, 122, 12427
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Diiron Azadithiolate Complexes with Bridging Phosphine Ligand dppf: Synthesis and Characterization

Xu-Feng Liu and Hao-Qi Gao

J Clust Sci, 2014, 25, 367
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Synthesis, characterization and electrocatalytic H2 production of base-containing Fe/S and Fe/Se clusters

Jin-Ping Li and Yao-Cheng Shi

Inorganica Chimica Acta, 2018, 482, 77
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Hydrogen generation: Aromatic dithiolate-bridged metal carbonyl complexes as hydrogenase catalytic site models

Indresh Kumar Pandey, Mookan Natarajan and Sandeep Kaur-Ghumaan

Journal of Inorganic Biochemistry, 2015, 143, 88
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New classification of cyclic P2N2-ligands predicting bridging and chelate coordination

Igor D. Strelnik, Tatiana P. Gerasimova, Kseniya A. Karasik, Igor A. Litvinov, Irina R. Dayanova, Kamil D. Ahmadgaleev, Alexey V. Kurenkov, Elvira I. Musina and Andrey A. Karasik

Inorganic Chemistry Communications, 2025, 172, 113638
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Synthesis, characterization and DFT studies of 1, 1′-Bis(diphenylphosphino)ferrocene substituted diiron complexes: Bioinspired [FeFe] hydrogenase model complexes

SANDEEP KAUR-GHUMAAN, A SREENITHYA and RAGHAVAN B SUNOJ

J Chem Sci, 2015, 127, 557
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New Systematic Route to Mixed-Valence Triiron Clusters Derived from Dinuclear Models of the Active Site of [Fe–Fe]-Hydrogenases

Laetitia Beaume, Martin Clémancey, Geneviève Blondin, Claudio Greco, François Y. Pétillon, Philippe Schollhammer and Jean Talarmin

Organometallics, 2014, 33, 6290
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Triiron Complexes Featuring Azadiphosphine Related to the Active Site of [FeFe]-Hydrogenases: Their Redox Behavior and Protonation

Ahmad Hobballah, Catherine Elleouet and Philippe Schollhammer

Molecules, 2024, 29, 3270
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Diiron Complexes [Fe2(CO)5(μ‐pdt/Mebdt)(L)] Containing a Chelating Diphosphine Ligand L=(Oxydi‐2,1‐phenylene)bis(diphenylphosphine): Bioinspired [FeFe] Hydrogenase Model Complexes

Indresh Kumar Pandey, Mookan Natarajan, Hemlata, Firasat Hussain and Sandeep Kaur‐Ghumaan

ChemistrySelect, 2016, 1, 5671
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Synthesis, characterization, and electrochemistry of five diiron propane-1,3-dithiolate complexes with substituted phosphine ligands

Lin Yan, Meng-Yuan Hu, Chao Mu, Ao Li, Xu-Feng Liu, Pei-Hua Zhao, Yu-Long Li, Zhong-Qing Jiang and Hong-Ke Wu

Journal of Coordination Chemistry, 2019, 72, 2499
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