A novel Cu(I)-based coordination polymer for efficient photocatalytic oxidation of C(sp3)–H bonds

Jiangtao Deng; Huilin Huang; Zhentao Li; Xu Jing; Chunying Duan

doi:10.1039/D4DT01257G

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A novel Cu(i)-based coordination polymer for efficient photocatalytic oxidation of C(sp³)–H bonds†

Jiangtao Deng,^a Huilin Huang,^a Zhentao Li,^a Xu Jing

*^a and Chunying Duan

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* Corresponding authors

^a State Key Laboratory of Fine Chemicals, College of Chemistry, Dalian University of Technology, P. R. China
E-mail: xjing@dlut.edu.cn

Abstract

A novel coordination polymer CuCl-Pyhc was successfully synthesized, which can catalyze efficient and selective oxidation of C(sp³)–H bonds under mild conditions, exhibiting exceptional stability and remarkable recyclability. Furthermore, CuCl-Pyhc can mimic natural monooxygenases and activate oxygen into singlet oxygen (¹O₂).

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Article information

DOI: https://doi.org/10.1039/D4DT01257G
Article type: Communication
Submitted: 29 apr 2024
Accepted: 28 mei 2024
First published: 03 jun 2024

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Dalton Trans., 2024,53, 10055-10059

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A novel Cu(I)-based coordination polymer for efficient photocatalytic oxidation of C(sp³)–H bonds

J. Deng, H. Huang, Z. Li, X. Jing and C. Duan, Dalton Trans., 2024, 53, 10055 DOI: 10.1039/D4DT01257G

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