Issue 24, 2023

Metallosupramolecular polymers: current status and future prospects

Abstract

Metallo-supramolecular polymers have gained increasing attention and witnessed continuous development as a vibrant new research interest in the domain of soft materials. These nonconventional polymers have found widespread application in materials and biology owing to their well-defined and diversified topologies and the distinct dynamic nature of the metallosupramolecular interactions against various stimuli. Because of the intriguing redox, photonic, electronic, and magnetic properties, these stimuli-responsive supramolecular structures have attracted considerable interest for optoelectronic device fabrication. However, it still remains challenging to develop stimuli responsive systems with offbeat applications. Furthermore, achieving spatiotemporal control remains elusive with thermoresponsive and sono-responsive metallosupramolecular polymers, which encounter the disadvantage of poor precision control. Additionally, controlling the morphology of these soft materials on the mesoscale, both in solution and on substrates, has many challenges. In this review, we discuss the recent developments and future directions for the construction of stimuli responsive metallosupramolecular systems targeting practical applications. Furthermore, we discuss the synthetic methodologies that have been used to regulate the mesoscale morphology of these materials, such as coordination modulation and pseudomorphic replication. Finally, we briefly cover the burgeoning field of programmed synthesis of metallosupramolecular polymers, emphasizing techniques, such as living polymerization and chemical fuel-driven transiently active systems, which we believe will be the major research directions in the future.

Graphical abstract: Metallosupramolecular polymers: current status and future prospects

Article information

Article type
Review Article
Submitted
24 aug 2023
First published
14 nov 2023

Chem. Soc. Rev., 2023,52, 8635-8650

Metallosupramolecular polymers: current status and future prospects

R. D. Mukhopadhyay and A. Ajayaghosh, Chem. Soc. Rev., 2023, 52, 8635 DOI: 10.1039/D3CS00692A

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements