Issue 11, 2017

Efficient carbon-supported heterogeneous molybdenum-dioxo catalyst for chemoselective reductive carbonyl coupling

Abstract

Reductive coupling of various carbonyl compounds to the corresponding symmetric ethers with dimethylphenylsilane is reported using a carbon-supported dioxo-molybdenum catalyst. The catalyst is air- and moisture-stable and can be easily separated from the reaction mixture for recycling. In addition, the catalyst is chemoselective, thus enabling the synthesis of functionalized ethers without requiring sacrificial ligands or protecting groups.

Graphical abstract: Efficient carbon-supported heterogeneous molybdenum-dioxo catalyst for chemoselective reductive carbonyl coupling

Supplementary files

Article information

Article type
Communication
Submitted
21 feb 2017
Accepted
07 mei 2017
First published
08 mei 2017

Catal. Sci. Technol., 2017,7, 2165-2169

Efficient carbon-supported heterogeneous molybdenum-dioxo catalyst for chemoselective reductive carbonyl coupling

S. Liu, J. Li, T. Jurca, P. C. Stair, T. L. Lohr and T. J. Marks, Catal. Sci. Technol., 2017, 7, 2165 DOI: 10.1039/C7CY00336F

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