Volume 186, 2016

How do polydisperse repulsive colloids crystallize?

Abstract

A modified version of the Gibbs-ensemble Monte-Carlo method reveals how polydisperse charged colloidal particles can build complex colloidal crystals. It provides general rules that are applicable to this fractionated crystallization that stems from size segregation. It explains the spontaneous formation of complex crystals with very large unit-cells in suspensions of nanoparticles with a broad size distribution.

Associated articles

Article information

Article type
Paper
Submitted
14 okt 2015
Accepted
04 nov 2015
First published
04 nov 2015

Faraday Discuss., 2016,186, 229-240

Author version available

How do polydisperse repulsive colloids crystallize?

R. Botet, B. Cabane, L. Goehring, J. Li and F. Artzner, Faraday Discuss., 2016, 186, 229 DOI: 10.1039/C5FD00145E

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