CH4 storage and CO2 capture in highly porous zirconium oxide based metal–organic frameworks

Qingyuan Yang; Vincent Guillerm; Florence Ragon; Andrew D. Wiersum; Philip L. Llewellyn; Chongli Zhong; Thomas Devic; Christian Serre; Guillaume Maurin

doi:10.1039/C2CC34714H

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CH₄ storage and CO₂ capture in highly porous zirconium oxide based metal–organic frameworks†‡

Qingyuan Yang,^ab Vincent Guillerm,^c Florence Ragon,^c Andrew D. Wiersum,^d Philip L. Llewellyn,^d Chongli Zhong,^a Thomas Devic,^c Christian Serre^c and Guillaume Maurin*^b

Author affiliations

* Corresponding authors

^a State Key Laboratory of Organic-Inorganic Composites, Beijing University of Chemical Technology, Beijing 100029, China

^b Institut Charles Gerhardt Montpellier, UMR CNRS 5253, UM2, Place E. Bataillon, 34095 Montpellier Cedex 05, France
E-mail: guillaume.maurin@univ-montp2.fr

^c Institut Lavoisier, UMR CNRS 8180-Université de Versailles StQuentin-enYvelines, 45 avenue des Etats-Unis, 78035 Versailles, France

^d Madirel UMR CNRS 7246, Universités Aix-Marseille - CNRS, Centre de Saint Jérôme, 13013 Marseille, France

Abstract

A series of porous Zr oxoclusters-based MOFs was computationally explored for their gas storage/capture performances. The highly porous UiO-67(Zr) and UiO-68(Zr) solids show exceptionally high CH₄ and CO₂ adsorption capacities under operating conditions that make these thermal, water and mechanical resistant materials very promising for physisorption-based processes.

This article is part of the themed collection: Metal-organic frameworks

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Article information

DOI: https://doi.org/10.1039/C2CC34714H
Article type: Communication
Submitted: 02 jul 2012
Accepted: 14 aug 2012
First published: 15 aug 2012

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Chem. Commun., 2012,48, 9831-9833

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CH₄ storage and CO₂ capture in highly porous zirconium oxide based metal–organic frameworks

Q. Yang, V. Guillerm, F. Ragon, A. D. Wiersum, P. L. Llewellyn, C. Zhong, T. Devic, C. Serre and G. Maurin, Chem. Commun., 2012, 48, 9831 DOI: 10.1039/C2CC34714H

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