Issue 58, 2012
From the journal:

Chemical Communications

Stepwise activation of “non-innocent” Cp* substituents – a Cp* based cascade reaction†‡

Markus Stubenhofer,a   Giuliano Lassandro,a   Gábor Balázs,a   Alexey Y. Timoshkinb  and  Manfred Scheer*a  

* Corresponding authors

a Institute of Inorganic Chemistry, University of Regensburg, D-93040 Regensburg, Germany
E-mail: manfred.scheer@chemie.uni-regensburg.de
Fax: +49 941 943 4439
Tel: +49 941 943 4440

b Department of Chemistry, St. Petersburg State University, University pr. 26, Old Peterhoff, St. Petersburg, Russia

Abstract

Reactions of Cp* substituted pentelidene complexes with the primary phosphine Cp*PH2 yield novel polycyclic phosphorus/arsenic and carbon containing cage compounds via cascade-like reactions. These reactions include a sequence of nucleophilic addition reactions, intramolecular hydrophosphination (partially hydroarsination) reactions, retro-Diels–Alder reactions with Cp*H elimination and subsequent [2+4]-cycloadditions.

Graphical abstract: Stepwise activation of “non-innocent” Cp* substituents – a Cp* based cascade reaction

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Article information

DOI
https://doi.org/10.1039/C2CC32690F
Article type
Communication
Submitted
16 apr 2012
Accepted
30 mei 2012
First published
31 mei 2012

Chem. Commun., 2012,48, 7262-7264

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Stepwise activation of “non-innocent” Cp* substituents – a Cp* based cascade reaction

M. Stubenhofer, G. Lassandro, G. Balázs, A. Y. Timoshkin and M. Scheer, Chem. Commun., 2012, 48, 7262 DOI: 10.1039/C2CC32690F

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