Issue 8, 2024

Assessing the aging and environmental implications of polyethylene mulch films in agricultural land

Abstract

Polyethylene mulch films (MFs) are widely employed in agricultural land to enhance crop yield and quality, but the MF residue causes significant environmental concerns. To promote the sustainable application of MFs, it is essential to assess their fate throughout their service life and understand the underlying degradation mechanisms. In this study, surface-exposed and soil-buried MFs were separately collected from agricultural land in Inner Mongolia, China. The variations in aging performance and corresponding property alterations of MF were thoroughly examined. The results indicated that sunlight exposure considerably hastens MF degradation, whereas buried MFs experience a more moderate aging process due to the inhibitory effects of the dark and anaerobic environment on oxidation. Surface cracking was observed in MF-Light samples as a result of photodegradation, while chemical and moisture interactions with soil caused partial perforation in MF-Soil samples. Relative to the pristine MF, the oxidation, unsaturation, and hydroxylation levels of MF-Light increased to 0.88, 0.35, and 0.73, respectively, with corresponding values for MF-Soil at 0.44, 0.13, and 0.24. The generated oxygen-containing functional groups lead to a decrease in contact angles of MF-Light and MF-Soil, enhancing their hydrophilicity. The aging process of MFs led to a decline in mechanical properties, posing challenges for recycling. Moreover, nearly all phthalate esters (PAEs) were released from MFs, regardless of sunlight exposure or soil burial. The use of MFs also impacted the abundance of soil microbial communities. Specifically, the selected polyethylene MF enriched Actinobacteriota by 75%, while reducing Chloroflexi and Firmicutes by 27% and 45%, respectively.

Graphical abstract: Assessing the aging and environmental implications of polyethylene mulch films in agricultural land

Article information

Article type
Paper
Submitted
28 feb 2024
Accepted
12 mei 2024
First published
21 mei 2024

Environ. Sci.: Processes Impacts, 2024,26, 1310-1321

Assessing the aging and environmental implications of polyethylene mulch films in agricultural land

C. Zhang, X. Liu, L. Zhang, Q. Chen and Q. Xu, Environ. Sci.: Processes Impacts, 2024, 26, 1310 DOI: 10.1039/D4EM00102H

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements