Issue 70, 2024

Unveiling the potential of triphenylphosphine salts in tuning organic room temperature phosphorescence

Abstract

Triphenylphosphine (TPP) salt derivatives, with their rich chemistry of core-substitution, have emerged as promising candidates for ultralong room temperature phosphorescence (RTP) materials owing to their distinct molecular structures, high quantum efficiency and exceptional phosphorescence properties. This feature article highlights the vast potential of TPP salt derivatives in tunable RTP properties by exploring some factors such as the alkyl chains, halogen anions, through-space charge transfer states, etc., and recent advancements in multi-level information encryption, high-level anticounterfeiting tags and X-ray imaging applications. We anticipate that this article will assist in directing future analyses based on the mechanisms underlying the RTP behavior of TPP derivatives and offer guidance for the rational design of high-performance RTP materials.

Graphical abstract: Unveiling the potential of triphenylphosphine salts in tuning organic room temperature phosphorescence

Article information

Article type
Feature Article
Submitted
27 jun 2024
Accepted
31 jul 2024
First published
01 aug 2024

Chem. Commun., 2024,60, 9328-9339

Unveiling the potential of triphenylphosphine salts in tuning organic room temperature phosphorescence

Y. Zhang, X. Wu, S. Liu, Y. Ma and Q. Zhao, Chem. Commun., 2024, 60, 9328 DOI: 10.1039/D4CC03156C

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