Post transition metal substituted Keggin-type POMs as thin film chemiresistive sensors for H2O and CO2 detection

Abigail A. Seddon; Nathan S. Hill; Osama El-Zubir; Andrew Houlton; R. John Errington; Pablo Docampo; Elizabeth A. Gibson

doi:10.1039/D3CC05660K

Post transition metal substituted Keggin-type POMs as thin film chemiresistive sensors for H₂O and CO₂ detection†

Abigail A. Seddon,

^a Nathan S. Hill,

^b Osama El-Zubir,^d Andrew Houlton,^d R. John Errington,

^a Pablo Docampo^c and Elizabeth A. Gibson

*^a

Author affiliations

* Corresponding authors

^a Energy Materials Laboratory, Chemistry, School of Natural and Environmental Sciences, Newcastle University, Newcastle upon Tyne, UK
E-mail: Elizabeth.gibson@newcastle.ac.uk

^b School of Mathematics, Statistics, and Physics, Newcastle University, Newcastle upon Tyne, UK

^c School of Chemistry, University of Glasgow, Glasgow, UK

^d Chemical Nanoscience Labs, Chemistry, School of Natural and Environmental Sciences, Newcastle University, Newcastle upon Tyne, UK
E-mail: osama.el-zubir@newcastle.ac.uk, andrew.houlton@newcastle.ac.uk

Abstract

Chemiresitive sensing allows the affordable and facile detection of small molecules such as H₂O and CO₂. Herein, we report a novel class of Earth-abundant post transition metal substituted Keggin polyoxometalates (POMs) for chemiresistive sensing applications, with conductivities up to 0.01 S cm⁻¹ under 100% CO₂ and 65% Relative Humidity (RH).

This article is part of the themed collections: Chemical Communications HOT Articles 2024 and Small Molecule Transformations of Energy Relevance

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Article information

DOI: https://doi.org/10.1039/D3CC05660K
Article type: Communication
Submitted: 17 nov 2023
Accepted: 15 jan 2024
First published: 16 jan 2024
This article is Open Access

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Chem. Commun., 2024,60, 1876-1879

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Post transition metal substituted Keggin-type POMs as thin film chemiresistive sensors for H₂O and CO₂ detection

A. A. Seddon, N. S. Hill, O. El-Zubir, A. Houlton, R. J. Errington, P. Docampo and E. A. Gibson, Chem. Commun., 2024, 60, 1876 DOI: 10.1039/D3CC05660K

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Chemical Communications