Issue 26, 2022

Potential application of metallacarboranes as an internal reference: an electrochemical comparative study to ferrocene

Abstract

Ferrocene and its derivatives have been extensively used as an internal reference in electrochemical processes. Yet, they possess limitations such as solvent restrictions that require chemical modifications. In this regard, we have studied the use of metallacarboranes [3,3′-M(1,2-C2B9H11)2] (M = Co, Fe) as general internal reference systems and have proven their suitability by thoroughly investigating their electrochemical properties in both aqueous and organic electrolytes without any derivatization.

Graphical abstract: Potential application of metallacarboranes as an internal reference: an electrochemical comparative study to ferrocene

Supplementary files

Article information

Article type
Communication
Submitted
21 jan 2022
Accepted
04 mrt 2022
First published
04 mrt 2022
This article is Open Access
Creative Commons BY-NC license

Chem. Commun., 2022,58, 4196-4199

Potential application of metallacarboranes as an internal reference: an electrochemical comparative study to ferrocene

J. A. M. Xavier, C. Viñas, E. Lorenzo, T. García-Mendiola and F. Teixidor, Chem. Commun., 2022, 58, 4196 DOI: 10.1039/D2CC00424K

This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence. You can use material from this article in other publications, without requesting further permission from the RSC, provided that the correct acknowledgement is given and it is not used for commercial purposes.

To request permission to reproduce material from this article in a commercial publication, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party commercial publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements