Issue 23, 2022

Circularly polarized luminescence from helical N,O-boron-chelated dipyrromethene (BODIPY) derivatives

Abstract

We report N,O-boron-chelated dipyrromethene derivatives exhibiting circularly polarized luminescence (CPL) in the red/near-infrared region, both in solution and the aggregated state. The CPL is originated from the helical chirality through intramolecular substitution of fluorine by an alkenolic substituent. The self-assembly of the fluorophores significantly enhances the |glum| values from 10−4 to 10−2.

Graphical abstract: Circularly polarized luminescence from helical N,O-boron-chelated dipyrromethene (BODIPY) derivatives

Supplementary files

Article information

Article type
Communication
Submitted
27 okt 2021
Accepted
21 feb 2022
First published
22 feb 2022

Chem. Commun., 2022,58, 3807-3810

Circularly polarized luminescence from helical N,O-boron-chelated dipyrromethene (BODIPY) derivatives

L. Wang, Z. Liu, K. Teng, L. Niu and Q. Yang, Chem. Commun., 2022, 58, 3807 DOI: 10.1039/D1CC06051A

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