Issue 30, 2021

A bench-stable N-trifluoroacetyl nitrene equivalent for a simple synthesis of 2-trifluoromethyl oxazoles

Abstract

ortho-Nitro-substituted N-trifluoroacetyl imino-λ3-iodane is a bench-stable trifluoroacetyl nitrene precursor, in which intra- and intermolecular halogen bonding (XB) plays an important role. Potential synthetic applications of this novel precursor were explored.

Graphical abstract: A bench-stable N-trifluoroacetyl nitrene equivalent for a simple synthesis of 2-trifluoromethyl oxazoles

Supplementary files

Article information

Article type
Communication
Submitted
14 mei 2021
Accepted
07 jul 2021
First published
07 jul 2021

Org. Biomol. Chem., 2021,19, 6628-6632

A bench-stable N-trifluoroacetyl nitrene equivalent for a simple synthesis of 2-trifluoromethyl oxazoles

Y. Kobayashi, S. Masakado, T. Murai, S. Hamada, T. Furuta and Y. Takemoto, Org. Biomol. Chem., 2021, 19, 6628 DOI: 10.1039/D1OB00947H

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