Issue 34, 2020
From the journal:

Organic & Biomolecular Chemistry

Boracene-based alkylborate enabled Ni/Ir hybrid catalysis†

Yukiya Sato,a   Yusuke Miyamoto,a   Yuto Sumida, ORCID logo *a   Takamitsu Hosoya ORCID logo bc  and  Hirohisa Ohmiya ORCID logo *ad  

* Corresponding authors

a Division of Pharmaceutical Sciences, Graduate School of Medical Sciences, Kanazawa University, Kanazawa 920-1192, Japan
E-mail: sumida@p.kanazawa-u.ac.jp, ohmiya@p.kanazawa-u.ac.jp

b Laboratory for Chemical Biology, RIKEN Center for Biosystems Dynamics Research (BDR), Kobe 650- 0047, Japan

c Laboratory of Chemical Bioscience, Institute of Biomaterials and Bioengineering, Tokyo Medical and Dental University (TMDU), Tokyo 101-0062, Japan

d JST, PRESTO, 4-1-8 Honcho, Kawaguchi, Saitama, Japan

Abstract

Boracene-based alkylborate enabled visible light-mediated metallaphotoredox catalysis. The directly excited borate was easily oxidatively quenched by an excited Ir photoredox catalyst. Ni/Ir hybrid catalysis afforded the products under significantly low irradiance.

Graphical abstract: Boracene-based alkylborate enabled Ni/Ir hybrid catalysis

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Article information

DOI
https://doi.org/10.1039/D0OB01610A
Article type
Communication
Submitted
05 aug 2020
Accepted
11 aug 2020
First published
11 aug 2020

Org. Biomol. Chem., 2020,18, 6598-6601

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Boracene-based alkylborate enabled Ni/Ir hybrid catalysis

Y. Sato, Y. Miyamoto, Y. Sumida, T. Hosoya and H. Ohmiya, Org. Biomol. Chem., 2020, 18, 6598 DOI: 10.1039/D0OB01610A

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