Issue 87, 2020

Mixed donor, phenanthroline photoactive MOFs with favourable CO2 selectivity

Abstract

Mixed donor phenanthroline-carboxylate linkers were combined with MnII or ZnII to form photoactive MOFs with large pore apertures. The MOFs display high CO2 adsorption capacities, which consequently causes structural framework flexibility, and align with favorable metrics for selective CO2 capture. The photophysical properties of the MOFs were investigated, with the MnII MOF giving rise to short triplet LMCT lifetimes.

Graphical abstract: Mixed donor, phenanthroline photoactive MOFs with favourable CO2 selectivity

Supplementary files

Article information

Article type
Communication
Submitted
23 aug 2020
Accepted
02 sep 2020
First published
02 sep 2020

Chem. Commun., 2020,56, 13377-13380

Mixed donor, phenanthroline photoactive MOFs with favourable CO2 selectivity

C. J. Setter, M. B. Price, L. Conte, W. Schmitt, S. R. Batten, C. Richardson, M. R. Hill, R. Babarao and L. K. Macreadie, Chem. Commun., 2020, 56, 13377 DOI: 10.1039/D0CC05715K

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