Issue 18, 2018

Observation of current rectification by a new asymmetric iron(iii) surfactant in a eutectic GaIn|LB monolayer|Au sandwich

Abstract

In this paper we expand on the search for molecular rectifiers of electrical current and report on a hexacoordinate metallosurfactant [FeIII(LN3O)(OMe)2], where (LN3O) is the deprotonated form of the new asymmetric ligand 2-((E)-((4,5-bis(2-methoxyethoxy)-2-(((E)-pyridin-2-ylmethylene)amino)phenyl)imino)methyl)-4,6-di-tert-butyl-phenol. This species rectifies current when deposited as a Langmuir–Blodget film in a “EGaIn/Ga2O3|LB|Au” sandwich with rectification ratios ranging from 25 to 300 at 1 Volt.

Graphical abstract: Observation of current rectification by a new asymmetric iron(iii) surfactant in a eutectic GaIn|LB monolayer|Au sandwich

Supplementary files

Article information

Article type
Paper
Submitted
09 feb 2018
Accepted
25 mrt 2018
First published
03 apr 2018

Dalton Trans., 2018,47, 6344-6350

Author version available

Observation of current rectification by a new asymmetric iron(III) surfactant in a eutectic GaIn|LB monolayer|Au sandwich

M. S. Johnson, C. L. Horton, S. Gonawala, C. N. Verani and R. M. Metzger, Dalton Trans., 2018, 47, 6344 DOI: 10.1039/C8DT00562A

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