Issue 24, 2017

Tunable luminescence and energy transfer properties of Bi3+ and Mn4+ co-doped Ca14Al10Zn6O35 phosphors for agricultural applications

Abstract

A series of Bi3+ and Mn4+ co-activated Ca14Al10Zn6O35 (CAZO) phosphors were synthesized using a solid state sintering method. The phase and morphologies of the CAZO based phosphors were confirmed using powder X-ray diffraction (XRD) and scanning electron microscopy (SEM), respectively. A novel phosphor CAZO:Bi3+ emits bright blue light under near-ultraviolet (NUV) excitation and its luminescence properties were characterized by diffuse reflectance and photoluminescence spectra. Tunable luminescence from blue to red was observed in Bi3+ and Mn4+ co-activated CAZO, which is attributed to energy transfer from Bi3+ to Mn4+. The energy transfer mechanism has been characterized by the decay times of the Bi3+ emission, which changes with the concentration of Mn4+. The energy transfer efficiency from Bi3+ to Mn4+ increases linearly with increasing the concentration of Mn4+. The as-obtained phosphor has a potential application in agricultural industry because the blue and red lights excited by NUV light emitting diodes (LEDs) are helpful for the improvement of photosynthesis.

Graphical abstract: Tunable luminescence and energy transfer properties of Bi3+ and Mn4+ co-doped Ca14Al10Zn6O35 phosphors for agricultural applications

Supplementary files

Article information

Article type
Paper
Submitted
31 jan 2017
Accepted
23 feb 2017
First published
06 mrt 2017
This article is Open Access
Creative Commons BY license

RSC Adv., 2017,7, 14868-14875

Tunable luminescence and energy transfer properties of Bi3+ and Mn4+ co-doped Ca14Al10Zn6O35 phosphors for agricultural applications

L. Li, Y. Pan, Z. Chen, S. Huang and M. Wu, RSC Adv., 2017, 7, 14868 DOI: 10.1039/C7RA01285C

This article is licensed under a Creative Commons Attribution 3.0 Unported Licence. You can use material from this article in other publications without requesting further permissions from the RSC, provided that the correct acknowledgement is given.

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