Issue 40, 2017

Recent advances in structural studies of heterometallic uranyl-containing coordination polymers and polynuclear closed species

Abstract

An overview is given of recent structural studies on heterometallic uranyl-containing species, with particular emphasis on those formed with carboxylate ligands, showing the effect of the additional metal cations and ancillary ligands on the dimensionality, geometry and topology of the assemblies generated. These examples illustrate the level of elaboration which is now possible in the design and synthesis of both uranyl clusters and coordination polymers, properties and potential applications of which are also briefly discussed.

Graphical abstract: Recent advances in structural studies of heterometallic uranyl-containing coordination polymers and polynuclear closed species

Article information

Article type
Frontier
Submitted
21 aug 2017
Accepted
13 sep 2017
First published
14 sep 2017

Dalton Trans., 2017,46, 13660-13667

Recent advances in structural studies of heterometallic uranyl-containing coordination polymers and polynuclear closed species

P. Thuéry and J. Harrowfield, Dalton Trans., 2017, 46, 13660 DOI: 10.1039/C7DT03105J

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