Issue 26, 2016

Inexpensive polyphenylene network polymers with enhanced microporosity

Abstract

Greatly enhanced microporosity is obtained for the amorphous porous polymers produced from the AlCl3-mediated coupling of aromatic hydrocarbons by using dichloromethane as the reaction solvent. A polymer of average BET surface area = 2435 m2 g−1 was obtained reproducibly from 1,3,5-triphenylbenzene with the additional porosity being provided as ultramicroporosity as demonstrated by very high CO2 adsorption at 273 K/1 bar.

Graphical abstract: Inexpensive polyphenylene network polymers with enhanced microporosity

Supplementary files

Article information

Article type
Communication
Submitted
19 apr 2016
Accepted
13 jun 2016
First published
17 jun 2016
This article is Open Access
Creative Commons BY license

J. Mater. Chem. A, 2016,4, 10110-10113

Inexpensive polyphenylene network polymers with enhanced microporosity

K. J. Msayib and N. B. McKeown, J. Mater. Chem. A, 2016, 4, 10110 DOI: 10.1039/C6TA03257E

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