Issue 22, 2015
From the journal:

RSC Advances

Photomagnetic molecular and extended network Langmuir–Blodgett films based on cyanide bridged molybdenum–copper complexes†

Nathalie Bridonneau,a   Jérôme Long,a   Jean-Louis Cantin,b   Jurgen von Bardeleben,b   Daniel R. Talham*c  and  Valérie Marvaud*a  

* Corresponding authors

a IPCM-CNRS-7201, UPMC-Univ Paris 6, cc 42, 4 place Jussieu, France
E-mail: valerie.marvaud@upmc.fr
Fax: +33 (0)1 44 27 38 41
Tel: +33 (0)1 44 27 32 77

b INSP-CNRS UMR-8232, UPMC-Univ. Paris 6, 4 place Jussieu, 75252 Paris Cedex 05, France

c Department of Chemistry, University of Florida, Gainesville, Florida 32611-7200, USA

Abstract

Two types of cyanide bridged molybdenum–copper photomagnetic films have been obtained: the first one is based on a molecular [MoCu6] complex, the other being a two-dimensional [MoCu2] coordination network. Both systems employ surfactant functionalized ligands and films were deposited on Melinex substrates using the Langmuir–Blodgett technique. All systems, including monolayer films, showed full retention of the intrinsic photomagnetic properties known for analogous solids as demonstrated by EPR spectroscopy.

Graphical abstract: Photomagnetic molecular and extended network Langmuir–Blodgett films based on cyanide bridged molybdenum–copper complexes

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Article information

DOI
https://doi.org/10.1039/C4RA16915H
Article type
Paper
Submitted
23 dec 2014
Accepted
28 jan 2015
First published
28 jan 2015

RSC Adv., 2015,5, 16696-16701

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Photomagnetic molecular and extended network Langmuir–Blodgett films based on cyanide bridged molybdenum–copper complexes

N. Bridonneau, J. Long, J. Cantin, J. von Bardeleben, D. R. Talham and V. Marvaud, RSC Adv., 2015, 5, 16696 DOI: 10.1039/C4RA16915H

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