Issue 8, 2015
From the journal:

Organic Chemistry Frontiers

The remarkable role of solvent in reaction mechanism studies by electrospray mass spectrometry

Hao-Yang Wang,*a   Jun-Ting Zhang,a   Shu-Sheng Zhanga  and  Yin-Long Guo*a  

* Corresponding authors

a National Center for Organic Mass Spectrometry in Shanghai, Shanghai Institute of Organic Chemistry, CAS, 345 Lingling Road, Shanghai, China 200032
E-mail: haoyangwang@sioc.ac.cn, ylguo@sioc.ac.cn
Fax: +86-21-54925314
Tel: +86-21-54925300

Abstract

The solvent requirements for an organic reaction are different from those of electrospray mass spectrometry (ESI-MS) analysis; therefore, some reaction solutions in non-ESI friendly solvents cannot be directly studied using ESI-MS. This mini account discusses some of our recent contributions in solving the challenging problems in the characterization of reactive intermediates in reaction solutions in non-ESI friendly solvents by using ESI-based mass spectrometry.

Graphical abstract: The remarkable role of solvent in reaction mechanism studies by electrospray mass spectrometry

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Article information

DOI
https://doi.org/10.1039/C5QO00154D
Article type
Tutorial Account
Submitted
12 mei 2015
Accepted
11 jun 2015
First published
12 jun 2015

Org. Chem. Front., 2015,2, 990-994

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The remarkable role of solvent in reaction mechanism studies by electrospray mass spectrometry

H. Wang, J. Zhang, S. Zhang and Y. Guo, Org. Chem. Front., 2015, 2, 990 DOI: 10.1039/C5QO00154D

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