Issue 7, 2014
From the journal:

Organic Chemistry Frontiers

Intermolecular reactions of gold(i)-carbenes with furans by related mechanisms†‡

David Lebœuf,§a   Morgane Gaydou,§a   Yahui Wanga  and  Antonio M. Echavarren*ab  

* Corresponding authors

a Institute of Chemical Research of Catalonia (ICIQ), Av. Països Catalans 16, 43007 Tarragona, Spain
E-mail: aechavarren@iciq.es

b Departament de Química Analítica i Química Orgànica, Universitat Rovira i Virgili, C/Marcel·li Domingo s/n, 43007 Tarragona, Spain

Abstract

The intermolecular gold(I)-catalyzed reactions of propargyl carboxylates, 1,6-enynes, or 7-substituted 1,3,5-cycloheptatrienes with furans afford cyclopentenones, polyenes or polycyclic compounds by related mechanisms initiated by the electrophilic addition of gold(I) carbenes to furans followed by ring-opening.

Graphical abstract: Intermolecular reactions of gold(i)-carbenes with furans by related mechanisms

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Article information

DOI
https://doi.org/10.1039/C4QO00130C
Article type
Research Article
Submitted
01 mei 2014
Accepted
18 jun 2014
First published
19 jun 2014
This article is Open Access
Creative Commons BY license

Org. Chem. Front., 2014,1, 759-764

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Intermolecular reactions of gold(I)-carbenes with furans by related mechanisms

D. Lebœuf, M. Gaydou, Y. Wang and A. M. Echavarren, Org. Chem. Front., 2014, 1, 759 DOI: 10.1039/C4QO00130C

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